Mercury fulminate is perhaps one of the oldest known initiating compounds. It can be detonated by either heat or shock, which would make it of infinite value to a terrorist. Even the action of dropping a crystal of the fulminate causes it to explode. A person making this material would probably use the following procedure:
MATERIALS EQUIPMENT ~~~~~~~~~ ~~~~~~~~~
mercury (5 g) glass stirring rod concentrated nitric 100 ml beaker (2) acid (35 ml)
adjustable heat source ethyl alcohol (30 ml)
blue litmus paper distilled water
funnel and filter paper
1) In one beaker, mix 5 g of mercury with 35 ml of concentrated nitric acid, using the glass rod.
2) Slowly heat the mixture until the mercury is dissolved, which is when the solution turns green and boils.
3) Place 30 ml of ethyl alcohol into the second beaker, and slowly and carefully add all of the contents of the first beaker to it. Red and/or brown fumes should appear. These fumes are toxic and flammable.
4) After thirty to forty minutes, the fumes should turn white, indicating that the reaction is near completion. After ten more minutes, add 30 ml of the distilled water to the solution.
5) Carefully filter out the crystals of mercury fulminate from the liquid solution. Dispose of the solution in a safe place, as it is corrosive and toxic.
6) Wash the crystals several times in distilled water to remove as much excess acid as possible. Test the crystals with the litmus paper until they are neutral. This will be when the litmus paper stays blue when it touches the wet crystals.
7) Allow the crystals to dry, and store them in a safe place, far away from any explosive or flammable material.
This procedure can also be done by volume, if the available mercury cannot be weighed. Simply use 10 volumes of nitric acid and 10 volumes of ethanol to every one volume of mercury.
3.13 NITROGLYCERINE
Nitroglycerine is one of the most sensitive explosives, if it is not the most sensitive. Although it is possible to make it safely, it is difficult. Many a young anarchist has been killed or seriously injured while trying to make the stuff. When Nobel's factories make it, many people were killed by the all-to-frequent factory explosions. Usually, as soon as it is made, it is converted into a safer substance, such as dynamite. An idiot who attempts to make nitroglycerine would use the following procedure:
MATERIAL EQUIPMENT ~~~~~~~~ ~~~~~~~~~ distilled water eye-dropper table salt 100 ml beaker sodium bicarbonate 200-300 ml beakers (2) concentrated nitric ice bath container acid (13 ml) ( a plastic bucket serves well ) concentrated sulfuric centigrade thermometer acid (39 ml) blue litmus paper glycerine
1) Place 150 ml of distilled water into one of the 200-300 ml beakers.
2) In the other 200-300 ml beaker, place 150 ml of distilled water and about a spoonful of sodium bicarbonate, and stir them until the sodium bicarbonate dissolves. Do not put so much sodium bicarbonate in the water so that some remains undissolved.
3) Create an ice bath by half filling the ice bath container with ice, and adding table salt. This will cause the ice to melt, lowering the overall temperature.
4) Place the 100 ml beaker into the ice bath, and pour the 13 ml of concentrated nitric acid into the 100 ml beaker. Be sure that the beaker will not spill into the ice bath, and that the ice bath will not overflow into the beaker when more materials are added to it. Be sure to have a large enough ice bath container to add more ice. Bring the temperature of the acid down to about 20 degrees centigrade or less.
5) When the nitric acid is as cold as stated above, slowly and carefully add the 39 ml of concentrated sulfuric acid to the nitric acid. Mix the two acids together, and cool the mixed acids to 10 degrees centigrade. It is a good idea to start another ice bath to do this.
6) With the eyedropper, slowly put the glycerine into the mixed acids, one drop at a time. Hold the thermometer along the top of the mixture where the mixed acids and glycerine meet. DO NOT ALLOW THE TEMPERATURE TO GET ABOVE 30 DEGREES CENTIGRADE; IF THE TEMPERATURE RISES ABOVE THIS TEMPERATURE, RUN LIKE HELL!!! The glycerine will start to nitrate immediately, and the temperature will immediately begin to rise. Add glycerine until there is a thin layer of glycerine on top of the mixed acids. It is always safest to make any explosive in small quantities.
7) Stir the mixed acids and glycerine for the first ten minutes of nitration, adding ice and salt to the ice bath to keep the temperature of the solution in the 100 ml beaker well below 30 degrees centigrade. Usually, the nitroglycerine will form on the top of the mixed acid solution, and the concentrated sulfuric acid will absorb the water produced by the reaction.
